UK Researchers Use Sunshine to Help Clean Water, Wastewater Safely

Sunlight combined with an inexpensive, harmless chemical could provide an environmentally safe way of destroying micro-pollutants in the environment.

UK researchers are developing a new type of reactor to destroy persistent contaminants such as pesticides and pharmaceutical residues using this innovative combination.

The technology breaks down the polluting molecules into carbon dioxide and water. This could provide a breakthrough for a sustainable way of cleaning up fresh water supplies and industrial wastewater.

The research team, led by Dr. Gianluca Li Puma at the University of Nottingham, is investigating a novel type of reactor – the "fountain photo-catalytic reactor" – to treat contaminated water using titanium dioxide.

The idea is to pump the contaminated water through a specially designed nozzle. Titanium dioxide is then added to the water.

The nozzle produces an umbrella-shaped fountain of water, with the sunlight – or artificial ultraviolet light – falling on the "canopy" of the umbrella.

This allows the photo-catalyst to absorb the solar radiation efficiently, resulting in a more effective destruction of the pollutants.

Dr Li Puma said, "Once the pollutants have been removed, the water can be passed to a settling tank where the titanium dioxide can be recovered and reused for the same process."

The team has successfully demonstrated the feasibility of the concept using a 400-liter pilot plant and ultraviolet lamps to simulate sunlight.

"We see this as being a potentially sustainable technology which could have particular use in countries with plenty of sunshine, such as southern Europe, Central and South America, Africa and the Asia Pacific region," said Dr Li Puma.

"In the UK, the present technology can use low cost, low power, sun-tanning lamps."

Certain pesticides and other chemicals, such as synthetic and human oestrogens, can persist in the environment.

"If these compounds find their way into water courses they can end up in rivers and accumulate in fish, causing ecological damage," said Dr Li Puma. "Some of these compounds are also potentially cancer-causing."

Water treatment plants usually use granular activated carbon to "soak up" these molecules. The carbon is then regenerated or disposed of by burning off the offending chemicals.

However, this can itself result in noxious chemicals entering the atmosphere, so the problem changes from one of water pollution to one of atmospheric pollution.

The process being tested by the Nottingham researchers is much gentler on the environment.

Titanium dioxide is an inexpensive white powder, which is used as pigment in paints and also in health products such as toothpastes and sunscreens.

Titanium dioxide is also a powerful photo-catalyst. It can take energy from sunlight and mediate the splitting of molecules.

Dr Li Puma said, "Titanium dioxide can absorb the ultraviolet component of sunlight, causing a change in its internal electron configuration … In this form it can split water into highly reactive components called free radicals."

One of these, the OH radical, readily reacts with large carbon-based molecules, such as pesticides, converting them into carbon dioxide and water.

The fountain photo-catalytic reactor can be easily installed in current water treatment works by the simple distribution of these nozzles in an open-air, sunlight-activated lagoon treatment plant.

In addition, the fountain photo-reactor has the potential to combine water disinfection and water detoxification in a single process.

The researchers are also investigating whether a similar technique could be used to disinfect water from wells, for example.

The project is funded by the Swindon based Engineering and Physical Sciences Research Council (EPSRC).

BBC News

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