Odor control technology roundup

July 25, 2023
A look at the technologies behind odor control in wastewater management and the solutions offered by companies today.

Odor control is often a necessary reality for wastewater utilities. Either to abide by local regulations or to maintain good community standing, utilities can find themselves working to mitigate odorous compounds in their collection systems, treatment facilities and solids handling facilities.

There are no federal regulations for odor control at wastewater treatment plants. However, left unhandled, odor can cause significant strain with nearby communities. States and communities have many unique regulations and requirements. Nationwide, though, the approaches to odor control use the same technologies.

Two Odor Control Approaches

To effectively control odors, wastewater utilities should first identify the cause of the nuisance odor and then identify the most effective technology to resolve it.

The most prominent compound responsible for odor is hydrogen sulfide. Other prominent compounds include methanethiol, ammonia, and volatile fatty acids. Many of these compounds are the byproducts of microbial activity, often under anaerobic conditions.

Odor control for wastewater collection and treatment includes two main approaches: vapor-phase technologies and liquid-phase technologies. Vapor-phase technologies control the odorous compounds in gasses and the air, while liquid-phase technologies control the compounds and microbial activity in the wastewater itself.

These two approaches each have their own host of unique solutions, as touched on below.

Vapor-phase Technologies

Vapor-phase technologies draw in and treat air from the sources of odorous compounds. These technologies are directly involved with ventilation to ensure that air is only discharged after treatment, often solubilizing the compounds.

Some prominent vapor-phase technologies to deal with wastewater odor control are as follows:

Wet air scrubbing is a vapor-phase odor control approach where the system adds the targeted compounds to a chemical solution. For example, sodium hydroxide or sodium hypochlorite can be used to solubilize hydrogen sulfide. A single-stage system can use a single solution to solubilize targeted compounds, whereas a multi-stage scrubber can treat the air through a series of treatments. The approach can treat for most prevalent odorous compounds.

Liquid redox uses an aqueous solution of chelated metal to remove hydrogen sulfide from a gas and convert it into solid, elemental sulfur. Compared to wet air scrubbing, liquid redox processes have higher capital costs but lower operating chemical costs.

Biofiltration uses microbes to solubilize multiple odorous compounds. They are effective at removing sulfur-based compounds, but not as effective at removing nitrogen-based compounds.

Solid scavengers convert sulfur compounds into more stable compounds through reactions that consume the medium itself. They are ideal for treating biogas with low to moderate levels of hydrogen sulfide.

Carbon adsorption systems attract multiple odorous compounds from the air, adhering them to its surface. It can remove hydrogen sulfide and other sulfur-based compounds well, but these systems are less effective at treating nitrogen-based compounds.

Liquid-phase Technologies

Liquid-phase technologies treat the wastewater stream itself to minimize the release of odorous compounds from the stream, often by adding chemicals to the wastewater.

Liquid-phase technologies are more often used in wastewater collection systems, rather than wastewater treatment plants. This treatment prevents hydrogen sulfide from escaping into the air, which also prevents corrosion. A single application point of liquid-phase technology can provide odor control for multiple odor release points, such as utility maintenance holes and re-pump stations.

Some prominent liquid phase technologies are:

Iron salts can oxidize or precipitate dissolved sulfide, turning it into ferrous sulfide and ferrous iron. At the treatment plant, aeration can then turn these compounds into sulfate and ferric iron. Iron salt solutions are classified as hazardous compounds and require appropriate handling.

Oxidation for odor control involves a strong chemical oxidizing agent, which chemically reacts with dissolved sulfide to convert it to sulfate or sulfur. The hazardous agent can also treat many other odorous and non-odorous compounds. One of the most commonly used oxidizers is hydrogen peroxide.

Lastly, the application of the chemical compound anthraquinone can also interrupt the processes of sulfate-reducing bacteria, controlling the presence of odor-causing sulfide.

Today’s Solutions

The market for wastewater odor control provides a number solutions for utilities to choose from, each providing a unique approach to specific odor control technologies. Some of today’s odor control solutions providers include:

SciCorp

SciCorp International Corp is a Canadian privately owned environmental technology company. SciCorp produces its own liquid plant based bioaugmentation products. The company has been in operation for 40 years and is currently active in 35 countries. It provides liquid micronutrient solutions to the wastewater treatment industry to eliminate odor at the source by reducing activity of odor producing microbes, while at the same time enhancing the performance and activity of non-odor producing microorganisms. The use of SciCorp’s technology also reduces energy consumed and biosolids produced, thereby reducing CO2 emissions and carbon footprint. SciCorp also claims that its solution improves treatment performance, increases capacity and reduces operating costs of WWTPs without additional capital expenditure.

www.scicorp.net

Kusters Water

Kusters Water, in conjunction with CSO Group Ltd., offers the Terminodour odor control technology. CSO Group has installed this technology at hundreds of plants throughout the world. This system offers a green solution to traditional odor control utilizing low amounts of electricity. The system can oxidize H2S at 50 ppm in a building and 500 ppm in a covered tank or wet well. It is capable of treating additional odorous compounds including VOC’s, organic acids, amines, mercaptans, ammonia and others.

www.kusterswater.com

Vapex Environmental

Vapex’s technology utilizes a patented process to treat hydrogen sulfide, mercaptans, amines and other odorous compounds found in municipal wastewater. The process creates hydroxyl radicals, a powerful oxidant, using only water and electricity. No additional chemicals or media are required. Hydroxyl radicals are so reactive that a small system can treat most of the odors gassed from wastewater, allowing the units to have a small footprint. The mist creating the radicals is sprayed into the enclosed space, oxidizing the odors in-situ rather than removing the air, leading to a low energy demand. In addition to eliminating odors, the technology also remediates fats, oils and grease (FOG), and kills sulfur reducing bacteria, decreasing the negative impacts of FOG buildup and lowering microbial induced corrosion. 

www.vapex.com

Veolia Water Technologies

Veolia’s Hydrex Sulfide Elimination System (HSES) is designed to combat hydrogen sulfide odors and corrosion. This odor control solution eliminates foul odors, reduces corrosion, and enhances overall operational efficiency. The system is available to treat H2S in solution or vapor phases in wastewater plants, lift stations, or other H2S generating areas. This two-step process uses environmentally sustainable and biodegradable chemistries to eliminate sulfides. 

The first step is a “reduction” step where a reagent is added and removes electrons from the sulfide molecule, converting the sulfide into inert and safe elemental sulfur that cannot reform into sulfide. The second step is a regenerative oxidation process, where the reagent reacts with an oxidant converting it back to its original form, ready to attack and reduce another sulfide molecule.  This process continually works to enable the rapid and efficient destruction of sulfide until H2S levels have been reduced to an acceptable level. 

www.watertechnologies.com  

About the Author

Jeremy Wolfe

Jeremy Wolfe is a former Editor for Wastewater Digest.

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